VITAMIN B 12 It is also known as Anti-pernicious anemia vitamin. It is a unique vitamin synthesized by only microorganisms and not by animals and plants. CHEMISTRY- The empirical formula of vitamin B12( cyanocobalamin) is C63H90N14O14PCo. The structure of vitamin B12 consist of corrin ring with a central cobalt atom. There are 2 coenzyme forms of vitamin B12 a) Methyl cobalamin In which cyanide is replaced by methyl group. b) 5-Deoxyadenosyl cobalamin- Cyanide is replaced by 5 deoxyadenosine forming an unusual carbon cobalt bond.  ABSORPTION, TRANSPORT AND STORAGE- The vitamin B12 is present in the diet in a bound form to proteins. B12 is liberated by the enzymes ( acid hydrolases) in the stomach. The dietary source of B12 is known as extrinsic factor of castle. The stomach secretes a special protein called intrinsic factor (IF). The cobalamin ...